Smith Lecture: The Plastics Electronics Revolution
Dr. Claus. Alan J. Heeger, winner of the 2000 Nobel Prize in Chemistry, looks a little like a thin Santa The similarity isn’t just the wispy white beard or cheerful demeanor—it’s the twinkle in his eyes when he shows you what his electronic polymers can do.
Heeger, a professor of physics at the University of California at Santa Barbara, was the guest of the Department of Physics and the Graduate School for their Annual Smith Lecture. On Wednesday, May 2, 2001, he enthralled his audience of nearly 450 with tales of the “fourth generation” of polymers. Heeger started with the basics for his audience by answering the question: What are polymers?
They are plastics—long chains of repeating molecules. They are strong, flexible, and can be made transparent. What makes them so strong? A carbon-to-carbon molecular bond. You know carbon. It’s the “C” on the Periodic Table of the Elements. It is also the stuff in diamonds.
The long chains of molecules bond strongly to each other, but interact weakly with other chains. Aligning these chains allows for their amazing strength and makes some plastics nearly impermeable: bulletproof vests are actually plastic, as are snow skis.
Plastics are everywhere. The insulation in your beverage cooler is made of plastic, the bread you buy at the grocery comes wrapped in plastic, some of the clothes you are wearing probably contain plastic, and if you’re reading this with carpet under your feet, guess what? It probably has plastic in it.
Three previous Nobel prizes have been awarded since 1953 for work done in plastics. The first plastics were insulators. Plastic is wrapped around conducting copper wires to protect those wires from the elements. But research in the late 70s and early 80s heralded new discoveries in polymer research. By altering the carbon bond structure, the plastic became a semi-conductor. Now, instead of protecting a copper wire, the polymer structure would behave like the copper wire.
What does that mean? We already have material that conducts—copper wires work quite well to transmit electricity. But polymers offer some unique advantages. The processing of polymers is much less expensive than processing metals. They weigh less and can be made stronger. “There is still lots of work to do,” said Heeger. “But there is the potential of developing polymers with the conducting property of copper and the strength of steel.”
First uses of the new plastics include light-emitting diodes, photo diodes, solar cells, circuits, and even lasers.
Heeger and his collaborators created a device that included a thin film of semi-conducting plastic on glass. How thin is thin? Heeger showed a diagram of the device, with the film layer labeled “1000 angstroms.” An angstrom is about the size of an atom. A layer one thousand angstroms thick is about 500 times smaller than a human hair.
The device can carry information by breaking the light into pixels through a series of columns and rows often called “passive addressing.” Colors of the light can be manipulated by changing the molecular structure. By creating information sources on the film, industrial applications are enormous. Already, cellular telephone displays are being made. The thin, flexible substrate used for these holds many advantages over traditional cellular phone displays: it’s light, thin, and doesn’t break easily.
Already, applications of the polymers are spawning new businesses. Uniax, a company founded by Heeger in 1990 and bought by Dupont in March 2000, created a beautiful replica of the Nobel medal—in a thin film of glowing plastic. “It runs on a battery,” said Heeger, showing it to his audience. “And will last about 20 hours.”
The future of these substances is limited only by our imaginations. Already, Heeger is working on colored liquid plastics that promise a revolution in the printing and circuitry worlds. “Let’s just call these colored liquids something we all know,” he said. “Ink. With a polymer ink that conducts, we can begin to print circuits.”
Heeger also introduced his audience to more applications: not only can these polymers emit light, they can detect it. Heeger showed a slightly grainy digital color image of a rose, scanned by a polymer photodiode.
“We are looking at a broad paradigm shift,” he said. “This new class of materials will be heavily used all over society. The semi-conducting property as well as processing and mechanical advantages will revolutionize many industries.”
Dr. Heeger asked one final question: was all this research worth it? He presented a picture of himself, seated beside Crown Princess Victoria of Sweden, “Yes!” he said.
Although Heeger admitted that he had had “quite a year” last year, between winning the Nobel and selling his company, he had to confess that this year is going well also. “Just before departing to come to Columbus,” he said, “I learned I’d been admitted to the National Academy of Sciences.”
The 2002 Smith Lecture was delivered by 2001 Nobel Laureate Eric Cornell. Details of his talk will be forthcoming in the January 2003 Ohio State Physics magazine.